Spring Coatings and Surface Treatments
Many spring coatings and spring surface treatments are available for metals. Some are primarily responsible for corrosion prevention while others are intended to improve the spring surface hardness or wear resistance. Spring coatings are also used to change dimensions (slightly) and to alter some physical properties such as reflectance and color. The chart below shows various types of spring coatings and spring treatments for metals.
Also, you can visit our spring materials page to learn more about selecting the right spring material for your application. Selecting the right spring material, finish, and surface treatment will ensure your spring design is optimized for the application. A Lee Spring engineer can assist with any technical questions.
Electropolishing
Electropolishing is used for polishing of metal parts. The principle is just the reverse of that of electroplating. The workpiece is made the anode in an electrolyte, with a cathode added to complete the electrical circuit. In the resulting deplating, material is removed most rapidly from raised, rough spots, producing a very smooth, polished surface. This process is primarily used for obtaining mirror-like surfaces from highly smooth initial surfaces. A final finish of less than 0.05 µm can be obtained if the initial surface roughness (root mean square) does not exceed 0.18 to 0.20 µm. Electropolishing is used for polishing stainless steel sheets and parts.
Tumbling
A tumbling (vibratory finishing) machine is an open-topped tub or bowl mounted on springs, usually lined with polyurethane. Vibratory action is created either by a vibratory motor attached to the bottom of the container, by a shaft or shafts with eccentric loads driven by a standard motor, or by a system of electromagnets. Tumbling can help to deburr metals, clean parts, or help to make a brighter spring finish.
Bowl vibrators are round bowl shaped and have a container mounted on springs. Vibratory action is imparted to the bowl by eccentric weights mounted on a vertical shaft at the center of the bowl. When activated, a spiral motion is imparted to the mass of parts and media. The major advantage of bowl vibrators is that an integral separation system can be incorporated. To separate parts from media, a dam is placed in the channel so that parts and media are forced up and over. At the top of the dam is a screen over which parts and media pass. Media fall through the screen back into the vibrator bowl. Parts are deflected off the screen into a collection hopper or conveyor.
Shot Peening
Shot peening is a method of cold working in which compressive stresses are induced in the exposed surface layers of metallic parts by a stream of shot, directed at the metal surface at high velocity under controlled conditions. It differs from blast cleaning in primary purpose and in the extent to which it is controlled to yield accurate and reproducible results. Although shot peening cleans the surface being peened, the major purpose of shot peening is to increase fatigue strength.
Media used for peening can be iron, steel, or glass shot, or cut steel or stainless steel wire. Metallic shot is designated by numbers according to size. Shot numbers, as standardized by MIL-S-13165, range from S70 to S780. The shot number is approximately the same as the nominal diameter of the individual pellets in ten thousandths of an inch. The effectiveness of the shotpeening operation is measured via the almen strip. This is a thin flat piece of steel that is clamped to a solid block and exposed to the blast of shot, which produces a curvature. The extent of this curvature on a standard sample serves as a means of measurement of the intensity of the peening.
Electroplating
Electroplating involves the creation of a galvanic cell in which the part to be plated is the cathode and the plating material is the anode. The two metals are placed in an electrolyte bath and a direct current applied from anode to cathode. Ions of the plating material are driven to the plating substrate through the electrolyte and cover the part with a thin coating of the plating material.
Steels, nickel and copper based alloys, as well as other metals are readily electroplated. Two approaches are possible. If a more noble (less active) metal is plated onto the substrate, it can reduce the tendency to oxidize as long as the plating remains intact to protect the substrate from the environment. Tin, nickel, and chromium are often used to electroplate steel for corrosion resistance. Chrome plating also offers an increase in surface hardness to HRC 70, which is above that obtainable from many hardened alloy steels. Unfortunately, any disruptions or pits in the plating can provide nodes for galvanic action if conductive media (such as rainwater) are present. Because the substrate is less noble than the plating, it becomes the sacrificial anode and rapidly corrodes. Electroplating with metals more noble than the substrate is seldom used for parts that will be immersed in water or other electrolytes.
Alternatively, a less noble metal can be plated onto the substrate to serve as a sacrificial anode which will corrode instead of the substrate. The most common example of this is zinc coating of steel, also called galvanizing. The zinc or cadmium coating will gradually corrode and protect the more noble steel substrate until the coating is used up, after which the steel will oxidize. Zinc coating can be applied by a process called "hot dipping" rather than by electroplating, which will result in a thicker and more protective coating recognizable by its "mother-of-pearl" appearance. A caution about electroplated coatings is that hydrogen embrittlement of the substrate can occur, causing significant loss of strength. Electroplated finishes should not be used on parts that are fatigue loaded. Experience has shown that electroplating severely reduces the fatigue strength of metals and can cause early failure.
Hydrogen Embrittlement - Whenever carbon steel is pickled in preparation for plating or during some electroplating processes, hydrogen can become absorbed into the material. While cracks can develop in the pickling or plating bath, more often they appear when the plated springs are in service. The hazard of hydrogen embrittlement becomes more acute when there is (1) high stress concentration, (2) high Rockwell hardness, or (3) high carbon content. Tempered materials are particularly susceptible. To relieve embrittlement, the springs must be baked immediately after plating to drive the hydrogen out of the material.
Electroless Plating
Electroless plating puts a coating of nickel on the substrate without any electric current needed. The substrate "cathode" in this case (there is no anode) acts as a catalyst to start a chemical reaction that causes nickel ions in the electrolyte solution to be reduced and deposited on the substrate. The nickel coating also acts as a catalyst and keeps the reaction going until the part is removed from the bath. Thus, relatively thick coatings can be developed. Coatings are typically between 0.001 in and 0.002 in thick. Unlike electroplating, the electroless nickel plate is completely uniform and will enter holes and crevices. The plating is dense and fairly hard at around 43 HRC. Other metals can also be electroless plated but nickel is most commonly used.
Chemical Coatings
The most common chemical treatments for metals range from a phosphoric acid wash on steel that provides limited and short-term oxidation resistance, to paints of various types designed to give more lasting corrosion protection. Black oxide is a lower cost option to form a corrosion protective barrier over various types of steel, stainless steel or copper substrates. Black oxide can also dull surfaces where light reflection is undesirable.
Platings | ||||||||
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Process | Commercial Specifications | Classes Available | Finishes/Grades Available | Chromate Conversion Colors Available | Primary Purpose | |||
Cadmium Plating |
QQ-P-416
AMS-QQ-P-416 |
Class I - 0.0005" minimum thickness Class II - 0.0003" minimum thickness Class III - 0.0002" minimum thickness |
Type I - As plated Type II - With chromate treatment Type III - With phosphate treatment |
Colorless Irridescent Bronze Brown Olive Drab Yellow Forrest Green |
Primarily used to protect steel and cast iron against corrosion. | |||
Chrome Plating |
QQ-C-320
AMS-QQ-C-320 |
Class I - Corrosion protective plating Class II - Engineering plating |
Type I - Bright Finish Type II - Satin Finish |
- | The metal so produced is extremely hard and corrosion resistant. The process is used for applications where excellent wear and/or corrosion resistance is required. | |||
Copper Plating |
MIL-C-14550B AMS 2418 |
Class 0 - 0.001" - 0.005" Thickness Class 1 - 0.001" minimum thickness Class 2 - 0.0005" minimum thickness Class 3 - 0.0002" minimum thickness Class 4 - 0.0001" minimum thickness |
- | - | Good corrosion resistance and conductivity. | |||
Gold Plating |
MIL-G-45204C |
Class 00 - 0.00002" minimum thickness Class 0 - 0.00003" minimum thickness Class 1 - 0.00005" minimum thickness Class 2 - 0.0001" minimum thickness Class 3 - 0.0002" minimum thickness Class 4 - 0.0003" minimum thickness Class 5 - 0.0005" minimum thickness Class 6 - 0.0015" minimum thickness |
Type I - 99.7% gold minimum Type II - 99.0% gold minimum Grade A - 90 Knoop maximum Grade B - 91 - 129 Knoop Grade C - 130 - 200 Knoop Grade D - 201 Knoop and over |
- | Good corrosion resistance and high tarnish resistance. Solderability and conductivity are excellent. | |||
Nickel Plating |
QQ-N-290
AMS-QQ-N-290 |
Class I - Corrosion protective plating Class II - Engineering plating |
Class I - Grade A through G (0.0016" - 0.0002" Thickness) |
- | Used extensively for decorative, engineering, and electroforming purposes. | |||
Silver Plating |
QQ-S-365D ASTM B700 |
Grade A - Chromate post-treatment Grade B - No supplementary treatment |
Type I - Matte finish Type II - Semi-bright finish Type III - Bright finish |
- | Good corrosion resistance and will tarnish easily. Solderability and conductivity are excellent. | |||
Tin Plating |
ASTM B545
MIL-T-10727C |
Type I - Electroplated Type II - Hot dipped |
- | - | Good corrosion resistance and excellent solderability. | |||
Vacuum Cadmium |
MIL-C-8837B AMS-C-8837 |
Class I - 0.0005" minimum thickness Class II - 0.0003" minimum thickness Class III - 0.0002" minimum thickness |
Type I - As plated Type II - With chromate treatment Type III - With phosphate treatment |
Colorless Irridescent Bronze Brown Olive Drab Yellow Forrest Green |
Primarily used to provide corrosion resistance to parts free from hydrogen contamination and possible embrittlement. | |||
Zinc Plating |
ASTM B633 |
Service Condition 1 (Fe/Zn 5) - mild conditions, 5μm thickness Service Condition 2 (Fe/Zn 8) - moderate conditions, 8μm thickness Service Condition 3 (Fe/Zn 12) - severe conditions, 12μm thickness Service Condition 4 (Fe/Zn 25)- very severe conditions, 25μm thickness |
Type I - As plated Type II - Colored chromate conversion coatings Type III - Colorless chromate conversion coatings Type IV - Phosphate conversion coating |
Colorless Blue Olive Drab Yellow |
Good corrosion resistance. |
Chemical Conversion Coatings | ||||||||
---|---|---|---|---|---|---|---|---|
Process | Commercial Specifications | Classes Available | Finishes/Grades Available | Chromate Conversion Colors Available | Primary Purpose | |||
Black Oxide |
MIL-C-13924 |
Class 1 - Alkaline oxidizing process Class 2 - Alkaline chromate oxidizing Class 3 - Fused salt oxidizing process Class 4 - Alkaline oxidizing process |
Supplementary oil treatment per
MIL-C-16173 |
- | A uniform, mostly decorative black coating. Limited corrosion resistance. | |||
Phosphate Coating (Light) |
TT-C-490E | - | Type I - Zinc phosphate spray application Zinc phosphate immersion or dip application Type II - Aqueous iron phosphate Type III - Organic pretreatment coating (MIL-C-8514) Type IV - DiscontinuedType V - Zinc phosphate |
- | Type I - All-purpose pretreatment prior to painting Type II and IV - For parts to be formed after painting Type III - Size and shape preclude Type I, II, IV Type V - Zinc phosphate |
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Phosphate Coating (Heavy) |
MIL-DTL-16232G |
Class 1 (Type M/Z) - Supplementary preservative treatment or coating Class 2 (Type M) - Supplementary treatment with lubricating oil Class 2 (Type Z) - Supplementary treatment with preservative Class 3 (Type M/Z) - No supplementary treatment Class 4 (Type M/Z) - Chemically converted (may be dyed to color as specified) |
Type M - Manganese Phosphate Base Type Z - Zinc Phosphate Base |
- | Coating for medium and low alloy steels. Intended as a base for supplemental coatings which provide the major portion of corrosion resistance. |
Electroless Plating | ||||||||
---|---|---|---|---|---|---|---|---|
Process | Commercial Specifications | Classes Available | Finishes/Grades Available | Chromate Conversion Colors Available | Primary Purpose | |||
Electroless Nickel |
MIL-C-26074F AMS 2404CAMS 2405B |
Class 1 - As plated Class 2 - Heat treated |
Grade A - 0.001" minimum thickness Grade B - 0.0005" minimum thickness Grade C - 0.0015" minimum thickness |
- | Used to deposit nickel without the use of an electric current. |
Lubrication | ||||||||
---|---|---|---|---|---|---|---|---|
Process | Commercial Specifications | Classes Available | Finishes/Grades Available | Chromate Conversion Colors Available | Primary Purpose | |||
Solid Film Lubrication |
MIL-L-46010 |
- | Color 1 - Natural product color Color 2 - Black |
- | Used to reduce wear and prevent galling, corrosion, and seizure of metals. |